I found a post on the NCRS Forum dated 2010 by Joe Lucia that states:
"Here's the deal: 1970 Corvettes with Q-Jet carbs used unique-to-that-year front retaining bolts for the carb. These were special bolts of GM #3967476. These bolts were 5/16-18 X 3-5/8". They had a flanged (washer) head. I do not know the material grade, finish, whether or not the head was trimmed or untrimmed, and what the across-the-flats (wrench) size was for these bolts.
So, why did they use these bolts for 1970? Well, it had to do with the NA-9 (California emissions) option. For cars equipped with this option, the front carb bolt holes were equipped with insulators. I expect that to improve retention of the insulators, the flanged head bolts were used. However. perhaps to simplify things, the same bolts were specified for all Q-Jet applications and not just those equipped with NA-9.
For early 1971, these bolts were replaced by GM #9432450. These are, from what I can tell, very similar bolts except that they are 3-3/4" long. They have a flanged head, phosphate finish, GM 280M material grade (SAE grade 5--3 lines), and untrimmed ("indented") head. I believe these are also the bolts used on the Oldsmobile applications that clem referred to.
In later 1971, these bolts were replaced in PRODUCTION by GM #9419047. These bolts are the same thread size and length as the 9432450. However, they are a NON-flanged head bolt. They were phosphate-finished and of GM 280-M material grade. I do not know if they had trimmed or untrimmed heads.
Why GM went back to the non-flanged head bolts during 1971 or why they ever used them for 1968-69 Q-Jets, I will never know. I TOTALLY agree with clem; the flanged head bolts should ALWAYS have been used with Q-Jets to avoid damage to the carb air horn. It was a DUMB thing for GM to use non-flanged head bolts for this application----just as dumb as using non flanged head bolts for small block intake manifolds and non-flanged head bolts for head bolts on both small and big blocks. DUMB!
By the way, all of the above-referenced bolts are discontinued and, as far as I know, not reproduced."
Other posts go on to agree that no washers were used by the factory with any of the four hold-down bolts or nuts. Of course, this information is specific to Corvettes of this era and may or may not apply to other models/years.